High Borosilicate Glass

- Feb 21, 2017-

History[edit]

Borosilicate glass was first developed by German glassmaker Otto Schott in the late 19th century. Otto Schott is also founder of today's SCHOTT AG, which has sold borosilicate glass under the brand nameDURAN since 1893. Another manufacturer of DURAN is the DURAN Group. After Corning Glass Works introduced Pyrex in 1915, the name became a synonym for borosilicate glass in the English-speaking world. However, borosilicate glass is the name of a glass family with various members tailoring completely different purposes. Most common today is borosilicate 3.3 glass like SCHOTT Duran and Pyrex by Corning.

The European manufacturer of Pyrex, Arc International, uses borosilicate glass in its Pyrex glass kitchen products;[1] however, the U.S. manufacturer of Pyrex kitchenware uses tempered soda-lime glass.[2]Thus Pyrex can refer to either soda-lime glass or borosilicate glass when discussing kitchen glassware, while Pyrex, Bomex, Duran, TGI and Simax all refer to borosilicate glass when discussing laboratory glassware. The real difference is the trademark and the company that owns the Pyrex name. The original Corning ware made of borosilicate glass was trademarked in capital letters (PYREX). When the kitchenware division was sold, the trademark was changed to lowercase (pyrex) and switched to low thermal-expansion soda-lime glass. The bottom of new kitchenware and old kitchenware can be inspected for an immediate difference.[citation needed] The scientific division of Pyrex has always been using borosilicate glass.[citation needed]

In addition to quartzsodium carbonate and aluminium oxide traditionally used in glassmaking, boron is used in the manufacture of borosilicate glass. The composition of low-expansion borosilicate glass, such as those laboratory glasses mentioned above, is approximately 80% silica, 13% boric oxide, 4% sodium oxide and 12–13% aluminium oxide. Though more difficult to make than traditional glass due to the high melting temperature required (Corning conducted a major revamp of their operations to manufacture it), it is economical to produce. Its superior durability, chemical and heat resistance finds excellent use in chemical laboratory equipment, cookware, lighting and, in certain cases, windows.

Physical characteristics[edit]

The common type of borosilicate glass used for laboratory glassware has a very low thermal expansion coefficient (3.3 × 10−6 K−1),[4] about one-third that of ordinary soda-lime glass. This reduces material stresses caused by temperature gradients, which makes borosilicate a more suitable type of glass for certain applications (see below). Fused quartzware is even better in this respect (having a fifteen times lower thermal expansion than soda-lime glass), however the difficulty of working with fused quartz makes quartzware much more expensive; borosilicate glass is a low-cost compromise. While more resistant to thermal shock than other types of glass, borosilicate glass can still crack or shatter when subjected to rapid or uneven temperature variations. When broken, borosilicate glass tends to crack into large pieces rather than shattering (it will snap rather than splinter).[5]

The softening point (temperature at which viscosity is approximately 107.6 poise) of type 7740 Pyrex is 820 °C (1,510 °F).[6]

Borosilicate glass is less dense (about 2.23 g/cm3) than typical soda-lime glass due to the low atomic mass of boron.

The temperature differential that borosilicate glass can withstand before fracturing is about 165 °C (329 °F). This compares well with soda lime glass, which can withstand only a 37 °C (99 °F) change in temperature and is why typical kitchenware made from traditional soda-lime glass will shatter if a vessel containing boiling water is placed on ice, but Pyrex or other borosilicate glass laboratory will not.[7]

Optically, borosilicate glasses are crown glasses with low dispersion (Abbe numbers around 65) and relatively low refractive indices (1.51–1.54 across the visible range).

Usage[edit]

Borosilicate glass has a wide variety of uses ranging from cookware to lab equipment, as well as a component of high-quality products such as implantable medical devices and devices used in space exploration

Health and science[edit]


Additionally, borosilicate tubing is used as the feedstock for the production of 
parenteral drug packaging, such as vials and pre-filled syringes, as well as ampoulesand dental cartridges. The chemical resistance of borosilicate glass minimizes the migration of sodium ions from the glass matrix, thus making it well suited forinjectable-drug applications. This type of glass is typically referred to as USP / EP JP Type I.Virtually all modern laboratory glassware is made of borosilicate glass. It is widely used in this application due to its chemical and thermal resistance and good optical clarity, but the glass can react with sodium hydride upon heating to produce sodium borohydride, a common laboratory reducing agent. Fused quartz is also found in some laboratory equipment when its higher melting point and transmission of UV are required (e.g. for tube furnace liners and UV cuvettes), but the cost and difficulty of working with quartz make it excessive for the majority of laboratory equipment.

Borosilicate is widely used in implantable medical devices such as prosthetic eyes, artificial hip joints, bone cements, dental composite materials (white fillings)[9]and even in breast implants.

Many implantable devices benefit from the unique advantages of borosilicate glass encapsulation. Applications include veterinary tracking devices, neurostimulators for the treatment of epilepsy, implantable drug pumps, cochlear implants, and physiological sensors.[10]

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